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ASTM E353-25

Standard Test Methods for Chemical Analysis of Stainless, Heat-Resisting, Maraging, and Other Similar Chromium-Nickel-Iron Alloys
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ASTM E353-25

Standard Test Methods for Chemical Analysis of Stainless, Heat-Resisting, Maraging, and Other Similar Chromium-Nickel-Iron Alloys

PUBLISH DATE 2025
PAGES 46
ASTM E353-25

1.1 These test methods cover the chemical analysis of stainless, heat-resisting, maraging, and other similar chromium-nickel-iron alloys having chemical compositions within the following limits:

Element Composition Range, %

  • Aluminum: 0.002 to 5.50
  • Boron: 0.001 to 0.20
  • Carbon: 0.01 to 1.50
  • Chromium: 0.01 to 35.00
  • Cobalt: 0.01 to 15.00
  • Niobium: 0.01 to 4.00
  • Copper: 0.01 to 5.00
  • Lead: 0.001 to 0.50
  • Manganese: 0.01 to 20.00
  • Molybdenum: 0.01 to 7.00
  • Nickel: 0.01 to 48.00
  • Nitrogen: 0.001 to 0.50
  • Phosphorus: 0.002 to 0.35
  • Selenium: 0.01 to 0.50
  • Silicon: 0.01 to 4.00
  • Sulfur: 0.002 to 0.50
  • Tantalum: 0.01 to 0.80
  • Tin: 0.001 to 0.05
  • Titanium: 0.01 to 4.50
  • Tungsten: 0.01 to 4.50
  • Vanadium: 0.005 to 1.00
  • Zirconium: 0.001 to 0.20

1.2 The test methods in this standard are contained in the sections indicated below:

  • Aluminum, Total, by the 8-Quinolinol Gravimetric Method (0.20 % to 7.00 %) – Sections 119–126
  • Aluminum, Total, by the 8-Quinolinol Spectrophotometric Method (0.003 % to 0.20 %) – Sections 71–81
  • Carbon, Total, by the Combustion–Thermal Conductivity Method – Discontinued 1986 – Sections 153–163
  • Carbon, Total, by the Combustion Gravimetric Method (0.05 % to 1.50 %) – Discontinued 2013 – Sections 98–108
  • Chromium by the Atomic Absorption Spectrometry Method (0.006 % to 1.00 %) – Sections 202–211
  • Chromium by the Peroxydisulfate Oxidation–Titration Method (0.10 % to 35.00 %) – Sections 212–220
  • Chromium by the Peroxydisulfate-Oxidation Titrimetric Method – Discontinued 1980 – Sections 145–152
  • Cobalt by the Ion-Exchange–Potentiometric Titration Method (2 % to 15 %) – Sections 53–60
  • Cobalt by the Nitroso-R-Salt Spectrophotometric Method (0.01 % to 5.0 %) – Sections 61–70
  • Copper by the Neocuproine Spectrophotometric Method (0.01 % to 5.00 %) – Sections 109–118
  • Copper by the Sulfide Precipitation-Electrodeposition Gravimetric Method (0.01 % to 5.00 %) – Sections 82–89
  • Lead by the Ion-Exchange-Atomic Absorption Spectrometry Method (0.001 % to 0.50 %) – Sections 127–136
  • Manganese by the Periodate Spectrophotometric Method (0.01 % to 5.00 %) – Sections 9–18
  • Molybdenum by the Ion Exchange–8-Hydroxyquinoline Gravimetric Method – Sections 242–249
  • Molybdenum by the Thiocyanate Spectrophotometric Method (0.01 % to 1.50 %) – Sections 190–201
  • Nickel by the Dimethylglyoxime Gravimetric Method (0.1 % to 48.0 %) – Sections 172–179
  • Phosphorus by the Alkalimetric Method (0.02 % to 0.35 %) – Sections 164–171
  • Phosphorus by the Molybdenum Blue Spectrophotometric Method (0.002 % to 0.35 %) – Sections 19–30
  • Silicon by the Gravimetric Method (0.05 % to 4.00 %) – Sections 46–52
  • Sulfur by the Gravimetric Method – Discontinued 1988 – Sections 30–36
  • Sulfur by the Combustion-Iodate Titration Method (0.005 % to 0.5 %) – Discontinued 2014 – Sections 37–45
  • Sulfur by the Chromatographic Gravimetric Method – Discontinued 1980 – Sections 137–144
  • Tin by the Solvent Extraction–Atomic Absorption Spectrometry Method (0.002 % to 0.10 %) – Sections 180–189
  • Tin by the Sulfide Precipitation-Iodometric Titration Method (0.01 % to 0.05 %) – Sections 90–97
  • Titanium by the Diantipyrylmethane Spectrophotometric Method (0.01 % to 0.35 %) – Sections 231–241
  • Vanadium by the Atomic Absorption Spectrometry Method (0.006 % to 0.15 %) – Sections 221–230

1.3 Test methods for the determination of carbon and sulfur not included in this standard can be found in Test Methods E1019.

1.4 Some of the composition ranges given in 1.1 are too broad to be covered by a single test method and therefore this standard contains multiple test methods for some elements. The user must select the proper test method by matching the information given in the Scope and Interference sections of each method with the composition of the alloy to be analyzed.

1.5 The values stated in SI units are to be regarded as standard.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 6 and in special “Warning” paragraphs throughout these test methods.

1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

4.1 These test methods for the chemical analysis of metals and alloys are primarily intended as referee methods to test such materials for compliance with compositional specifications, particularly those under the jurisdiction of ASTM Committee A01 on Steel, Stainless Steel, and Related Alloys.

It is assumed that all who use these test methods will be trained analysts capable of performing common laboratory procedures skillfully and safely. It is expected that work will be performed in a properly equipped laboratory under appropriate quality control practices such as those described in Guide E882.
SDO ASTM: ASTM International
Document Number E353
Publication Date May 15, 2025
Language en - English
Page Count 46
Revision Level 25
Supercedes
Committee E01.01

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