BSI PD CEN/TS 17764:2022

Current Revision
Inorganic micronutrient fertilizers. Determination of the concentration of free, chelated or complexed micronutrients and the chelating and/or complexing agents present in compound inorganic micronutrient fertilizers

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BSI PD CEN/TS 17764:2022

Inorganic micronutrient fertilizers. Determination of the concentration of free, chelated or complexed micronutrients and the chelating and/or complexing agents present in compound inorganic micronutrient fertilizers

PUBLISH DATE 2022
PAGES 18
BSI PD CEN/TS 17764:2022

This document specifies the method for the determination of free, chelated or complexed micronutrients and chelating and/or complexing agents present in compound inorganic micronutrient fertilizers. This method applies to compound inorganic micronutrient fertilizers when micronutrients are chelated and/or complexed.

The method is based on the determination of the following specific parameters :

  • the water-soluble micronutrient concentration;
  • the fraction of chelated micronutrients in relation;
  • identification of chelating agents EDTA, DTPA, HEEDTA, IDHA, [S,S]–EDDS, [o,o] EDDHA, [o,o] EDDHMA, [o,p] EDDHA, HBED and EDDHSA;
  • the fraction of complexed micronutrients;
  • identification of complexing agents (lignosulfonates, heptagluconic acid (HGA)).

The method is based on :

  • ICP (inductive coupled plasma) or FAAS (flame atomic absorption spectrometry) measurement of the concentration of water-soluble micronutrients according to EN 16963 or EN 16965 after extraction according to EN 16962;
  • LC (liquid chromatography) measurement of the chelating agents according to EN 15950, EN 13368-1, EN 13368-2, EN 13368-3, EN 15451, EN 15452; and/or complexing agents according to EN 16109 and EN 16847;
  • determination of the concentration of chelated micronutrients by CEN/TS 17786-1 and/or CEN/TS 17786-2;
  • determination of the complexed micronutrients by EN 15962.

To avoid duplication of the analytical methods, CEN/TS 17786-2 describes the determination of micronutrients and the identification and determination of chelating agents.

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