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Environmental solid matrices - Determination of elemental composition by X-ray fluorescence spectrometry
This document specifies the procedure for a quantitative determination of major and trace element concentrations in homogeneous solid waste, soil, soil-like material and sludge by energy dispersive X-ray fluorescence (EDXRF) spectrometry or wavelength dispersive X-ray fluorescence (WDXRF) spectrometry using a calibration with matrix-matched standards.
This document is applicable for the following elements:
Concentration levels between a mass fraction of approximately 0,000 1 % and 100 % can be determined depending on the element and the instrument used.
An optional XRF screening method for solid and liquid material as waste, sludge and soil is added in Annex A which provides a total element characterization at a semi-quantitative level, where the calibration is based on matrix-independent calibration curves, previously set up by the manufacturer.
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